d Orbital Energies for Various Structures in Terms of Dqo
Coordination Number | Structure | dx2 - y2 | dz2 | dxy | dxz | dyz
|
2 | lineara | -6.28 | 10.28 | -6.28 | 1.14 | 1.14 |
3 | trigonalb | 5.46 | -3.21 | 5.46 | -3.86 | -3.86 |
4 | tetrahedrala | -2.67 | -2.67 | 1.78 | 1.78 | 1.78 |
4 | square planarb | 12.28 | -4.28 | 2.28 | -5.14 | -5.14 |
5 | trigonal bipyramidc | 0.82 | 7.07 | -0.82 | -2.72 | -2.72 |
5 | square pyramidc | 9.14 | 0.86 | -0.86 | -4.57 | -4.57 |
6 | octahedron | 6.00 | 6.00 | -4.00 | -4.00 | -4.00 |
aBonds lie along the z axis
bBonds lie in the xy plane
cPyramid base in the xy plane
From "Theoretical Inorganic Chemistry," M. Clyd Day and Joel Selbin, Reinhold Publishing Corp., New York (1962), p 292.